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1 article(s) from Minuth, Tobias

Bis(oxazolines) based on glycopyranosides – steric, configurational and conformational influences on stereoselectivity

Tobias Minuth and
Mike M. K. Boysen

Beilstein J. Org. Chem. 2010, 6, No. 23, doi:10.3762/bjoc.6.23

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Scheme 1: New glucosamine-based bis(oxazoline) ligands with their pyranose conformation and application in as...

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Figure 1: Planned modifications at pyranose position 3 of carbohydrate bis(oxazolines).

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Scheme 2: Synthesis of allo-configured bis(oxazolines) 3-O-Ac alloBox (14) and Ac alloBox (16) from thiogluco...

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Scheme 3: Preparation of ligands 3-deoxy glucoBox (21) and Ac 3-deoxy glucoBox (23) from key intermediate 7.

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Scheme 4: Preparation of ligand 3-O-Formyl glucoBox (26) from bis(amide) 24.

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Figure 2: Impact of structural ligand modifications on the stereoselectivity of cyclopropanations.

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Published 04 Mar 2010

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